Theoretical energy storage density of graphene supercapacitors

What is the energy density of graphene supercapacitors?

In practice, the energy density of graphene supercapacitors achieved so far is between 15 and 35 Wh kg−1, and less than 60 Wh l−1.

How can graphene supercapacitors improve volumetric performance?

Graphene supercapacitors can enhance their volumetric performance by controlling the density of the graphene electrodes. This results in ultrahigh energy densities of up to 60 Wh l −1, comparable to lead–acid batteries.

What is the specific capacitance of a 3D graphene scaffold?

The nanocomposite resulted in a high specific capacitance of 533 F g −1, an energy density of 36.6 W h kg −1 at a power density of 1.2 kW kg − 1. GFs with a 3D graphene scaffold have gained attention as suitable candidates for SC electrodes.

What is the energy density of a supercapacitor?

A supercapacitor with graphene-based electrodes was found to exhibit a specific energy density of 85.6 Wh/kg at room temperature and 136 Wh/kg at 80 °C (all based on the total electrode weight), measured at a current density of 1 A/g.

Can graphene be used in supercapacitors?

Recently, composites made of graphene have been researched to achieve exceptional electrochemical performance. 22–26 Due to its poor EDLC-type nature, the use of graphene as electrodes in supercapacitors is constrained by low capacitance and low energy density.

What limits graphene's volumetric energy density?

The macroporous nature of graphene limits its volumetric energy density. Graphene has a much lower capacitance than the theoretical capacitance of 550 F g −1 for supercapacitors and 744 mA h g −1 for lithium ion batteries.